![]() ![]() Wolff A, Doert T, Hunger J, Kaiser M, Pallmann J, Reinhold R, Yogendra S, Giebeler L, Sichelschmidt J, Schnelle W, Whiteside R, Gunaratne H Q N, Nockemann P, Weigand J J, Brunner E and Ruck M 2018 Low-temperature tailoring of copper-deficient Cu 3−xP-electric properties, phase transitions, and performance in lithium-ion batteries Chem. Wang R, Dong X-Y, Du J, Zhao J-Y and Zang S-Q 2018 MOF-Derived Bi-functional Cu 3P nanoparticles coated by a N, P-Co-doped carbon shell for hydrogen evolution and oxygen reduction Adv. Zheng H, Huang X, Gao H, Lu G, Dong W and Wang G 2019 3P Core–shell nanowires attached to nickel foam as high-performance electrocatalysts for the hydrogen evolution reaction Chem. Hua S, Qu D, An L, Jiang W, Wen Y, Wang X and Sun Z 2019 Highly efficient p-type Cu 3P/n-type g-C 3N 4 photocatalyst through Z-scheme charge transfer route Appl. Kong M, Song H and Zhou J 2018 Metal–organophosphine framework-derived N,P-codoped carbon-confined Cu 3P nanopaticles for superb Na-ion storage Adv. Shen R, Xie J, Ding Y, Liu S-y, Adamski A, Chen X and Li X 2019 Carbon nanotube-supported Cu 3P as high-efficiency and low-cost cocatalysts for exceptional semiconductor-free photocatalytic H 2 evolution ACS Sustain. Hao J, Yang W, Huang Z and Zhang C 2016 Superhydrophilic and superaerophobic copper phosphide microsheets for efficient electrocatalytic hydrogen and oxygen evolution Adv. Wolff A, Pallmann J, Boucher R, Weiz A, Brunner E, Doert T and Ruck M 2016 Resource-efficient high-yield ionothermal synthesis of microcrystalline Cu 3−xP Inorg. 11 441īera D, Qian L, Tseng T K and Holloway P H 2010 Nanocrystals for thin film photovoltaic applications quantum dots and their multimodal applications: a review Materials 3 2260 38 39īachmann K J 1981 Properties, preparation, and device applications of indium phosphide Annu. Luber E J, Mobarok M H and Buriak J M 2013 Solution-processed zinc phosphide (α-Zn 3P 2) colloidal semiconducting nanocrystals for thin film photovoltaic applications ACS Nano 7 8136īhushan M and Catalano A 1981 Polycrystalline Zn 3P 2 Schottky barrier solar cells Appl. Glynn (ed.), Proceedings of SPIE Opto-Ireland 2002: Optics and photonics technologies and applications Vol. ![]() Greuters J and Rizvi N 2003 UV laser micromachining of silicon, indium phosphide and lithium niobate for telecommunications applications. Miao S, Hickey S G, Rellinghaus B, Waurisch C and Eychmüller A 2010 Synthesis and characterization of cadmium phosphide quantum dots emitting in the visible red to near-infrared J. Sun M, Liu H, Qu J and Li J 2016 Earth-rich transition metal phosphide for energy conversion and storage Adv. Wei K, Qi K, Jin Z, Cao J, Zheng W, Chen H and Cui X 2016 One-step synthesis of a self-supported copper phosphide nanobush for overall water splitting ACS Omega 1 1367ĭu H, Kong R-M, Guo X, Qu F and Li J 2018 Recent progress in transition metal phosphides with enhanced electrocatalysis for hydrogen evolution Nanoscale 10 21617 Graphic abstractĬallejas J F, Read C G, Roske C W, Lewis N S and Schaak R E 2016 Synthesis, characterization, and properties of metal phosphide catalysts for the hydrogen-evolution reaction Chem. To the best of our knowledge, this is the first report on rare-earth doped Cu 3P nanoparticles and shows promise on the luminescence aspect of Cu 3P nanomaterials along with its already existing plasmonic and semiconducting properties. However, on doping the rare-earth ions (RE 3+ = Ce 3+/Tb 3+) in the Cu 3P NCs show the green luminescence (at 542 nm) which is attributed to the emission of Tb 3+ ions. HRTEM images reveal that spherical-shaped particles on further agglomeration through Ostwald ripening process form hexagonal-shaped bigger microstructures. At higher phosphorus concentration, hexagonal shaped micro-crystals with prominent grain are observed. However, bigger size (41.9 nm) and tensile lattice strains are obtained for the lower concentration of phosphorous (5 times). For example, smaller crystallite size (38.5 nm) and compressive lattice strain are obtained when 10 times of red phosphorous is used. In the presence of IL, crystallite size and lattice strain significantly change with changing the concentration of red phosphorus. Effect of ILs and precursor concentration on crystal phase, crystallite size, lattice strain, morphology and grain size of Cu 3P NCs is studied. Herein, ionic liquids (ILs) are used as a structure directing/templating agent. Highly crystalline, phase pure Cu 3P nanocrystals (NCs) have been successfully synthesized using ionic liquid-assisted solvothermal method at relatively low temperature (200 ☌). ![]()
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